olivine

A series of solid phases (mixed lithium-iron-manganese phosphates) of the common formula LiMnyFe1−yPO4 (0 ≤ y ≤ 1) with a carbon coating on the particle surface was synthesized by mechanochemical activation with carbothermal reduction. The synthesized mixed phosphates were examined as promising cathode materials for lithium-ion batteries. The positive effect of replacement of a rather small fraction of iron by manganese is shown, which improves the electrochemical performance at the rates C/10–10C.

The use of aqueous electrolyte in lithium-ion energy storage systems can choose some of the problems associated with the use of electrolytes based on organic solvents, such as a risk of ignition of an abnormal violation of tightness and the sensitivity of operational parameters to production conditions. As part of the development of one of these systems, LiTi2(PO4)3 | aqueous Li2SO4 (1 mol·l −1 ) | LiFePO4, a technique for their implementation in the form of prototypes made using a film for lamination using an office laminator is proposed.