ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

cathode materials; layered structure

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The characterization of the electronic state of transition metal ions occuring in the Li1 + xNi1/3Co1/3Mn1/3O2 by magnetic methods

The complex oxides Li1 + xNi1 / 3Co1 / 3Mn1 / 3O2 were obtained by solid state method. The conclusion about influence of lithium concentration on Ni2+ and Ni3+ ions ratio in Li1 + xNi1 / 3Co1 / 3Mn1 / 3O2 is made. Monotonous decrease of g-factor value identified by EPR method testifies the intensification of local exchange interactions with temperature descent.