ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

For citation:

Sofronova T. V., Moiseev G. K., Bushkova O. V., Zhukovskii V. M. Composition and thikness of the passivating films, formed upon lithium contact with the gas of various compositions (computer simulation). Electrochemical Energetics, 2003, vol. 3, iss. 1, pp. 7-?.

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Language: 
Russian
Article type: 
Article

Composition and thikness of the passivating films, formed upon lithium contact with the gas of various compositions (computer simulation)

Autors: 
Sofronova T. V., Institute of Metallurgy UB of RAS
Moiseev G. K., Institute of Metallurgy UB of RAS
Bushkova Ol'ga Viktorovna, Institute of Solid State Chemistry
Zhukovskii V. M., The Ural State University of A. M. Gorky
Abstract: 

The potentialities of numerical simulation and prediction of the equilibrium chemical composition and the thickness of surface films formed on solid lithium upon its contact with gas were demonstrated. The composition and the thickness of the films formed upon the contact of lithium with Н2 N2, O2, F2, Cl2, Н20, СН2, NH2, С2Н2, H2S, СO2, СО, NO2, SO2, CN, dry and humid air had been calculated. The films were considered as disordered mediums, and the effective interaction radii of the product molecules (Onsager's radii) which arc their generalized statistical characteristics were calculated.