ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


диффузия ионов лития

The kinetic of lithium ions intercalation in the anatase synthesized by sol-gel methods

Possibility of ultradispersed TiO22 (anatase modification) using as the base of the lithium power sources cathode material obtained by chloride-acid hydrolysis of titanium tetrachloride has been studied. The researches of Li+ ions electrochemical intercalation kinetics and phasic model of the process was suggested. The cathode material phase composition changes during discharge were fixed and interpreted.

Peculiarities of the kinetic laws of cathode synthesis of the Cu–Pb–Bi–Ca system designed for using as an anode of a metal-ion battery

Matrix electrodes based on copper and lead were obtained by cathode intercalation: CuBi, PbBi, CuPbBi, CuCa, PbCa, CuBiCa, PbBiCa, CuPbBiCa, their composition being identified by means of X-ray diffraction analysis and open-circuit potential measurement. The laser emission micro-spectral analysis determines the depth of penetration (% of mass) of cations of bismuth, lead and calcium into the structure of the electrodes under study.