ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


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Investigation into capabilities of nickel-metall hydride battery with bipolar electrodes and common gas collector

The mock-up of nickel-metal hydride storage battery of filter-press type with rated voltage of 6 V and capacity of 1.7 A·h is assembled and tested. The capability of storage battery operation with bipolar nickel-metal hydride electrodes in a single case with common gas collector is demonstrated, and the problems, consideration of which will enable to enter on a battery prototype stage, are defined.

Possibility of thermal runaway in the lamellar nickel-cadmium accumulators

The probability of the thermal runaway in nickel-cadmium accumulators with lamellar electrodes has been studied experimentally. It has been shown that in electrodes of these accumulators that have long terms of service there is a great amount of hydrogen just as in the accumulators with metal-ceramic and striking electrodes. However, the thermal runaway in nickel-cadmium accumulators with lamellar electrodes is less probable than in the accumulators with metal-ceramic and striking electrodes.

New ways to improve the performance of sealed batteries of high capacity

Herein are considered some ways to improve the performance efficiency of sealed batteries of high capacity by providing uniform electrolyte distribution with battery height, increasing active mass utilization coefficient and limiting PCL effect.

Studying kinetics of oxidation of glucose by bacterial cells Escherichia Coli by means of a method of a rotating disk electrode

The method of a rotating disk electrode leads studying the basic laws of electrochemical behaviour of mediator as basic electroactive component of bioelectrochemical system and influence of speed of rotation of an electrode, concentration of mediator, glucose and microbial cells are certain for the general speed of process bioelectrocatalitic oxidation of glucose.

Influence of some components of lead-antimony and lead-calcium alloys on their mechanical and corrosion properties

The influence of the concentration of antimony, tin, cadmium, calcium, silver, and barium on some characteristics of lead-antimony and lead-calcium alloys was studied. The cadmium-doped and barium-doped alloys show the best corrosion resistance among the lead-antimony and lead-calcium alloys, respectively.

New additives to active masses and electrolyte of sealed lead storage battery

Effect of high-collated carbon clusters (soots containing fullerenes and nanopipes) on electrode pastes structure have been studied and their positive effect on characteristics of the obtained active masses has been shown. Effect of partial hydrophobization of negative active mass (NAM) on efficiency of the closed oxygen cycle has been studied. Effect of different additives (С7H6O2, C8H8O2, (-CF3-CF25-)QZ) on ?H2 have been studied.

Treatment optimization of the positive active masses of alkaline batteries

The concept of processing of the positive electrode material taken from fulfilled alkaline accumulators, based on primary separation of an iron component from nickel at stages of hydrometallurgical repartition, is presented..

Performance of free-breathing PEM FC in limited-volume conditions

This paper represents performance of air-hydrogen free-breathing Fuel Cell (FC) in limited volume conditions. Research work was carried out with thin two-cell stacks related to use in prototype of particular power source system, which includes aluminium-water microgenerator of hydrogen. In small current densities field (<200 mA/cm2) it was established, that after FC had been confined within the small volume, characteristics of FC became better than in non-limited-volume conditions due to self humidification.

Lithium intercalation into thin-film lithium-tin and lithium-carbon electrodes: an impedance spectroscopy study

Reversible lithium intercalation from a non-aqueous electrolyte into thin films of tin (0.1–1 mcm) and carbon (-3 mcm) was studied by means of electrode impedance spectroscopy. The measurements were made within a frequency range of 105–10-2 Hz at a varying lithium concentration in the matrix. The paper discusses several versions of electrical equivalent circuits to simulate the experimental impedance spectra, and the concentration dependence of the lithium diffusion coefficient.

Optimisation of electrode pasting technology

The production of pasted electrodes has been analysed. The equation which connects paste rheology, porous matrix and technologic parameters has been obtained. The approach optimises pasted electrode technology.

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