Для цитирования:
Истомина А. С., Бушкова О. В. Полимерные связующие для электродов литиевых аккумуляторов. Часть 2. Синтетические и природные полимеры // Электрохимическая энергетика. 2020. Т. 20, вып. 4. С. 175-?. DOI: 10.18500/1608-4039-2020-20-4-175-205, EDN: ICQJOJ
Полимерные связующие для электродов литиевых аккумуляторов. Часть 2. Синтетические и природные полимеры
Во второй части обзора обсуждаются перспективы использования альтернативных полимерных связующих для композиционных электродов литиевых электрохимических систем. Среди возможных вариантов рассмотрены наиболее популярные коммерчески доступные синтетические полимеры с функциональными группами (преимущественно образующие водные растворы или дисперсии) и водорастворимые полимеры природного происхождения. Отличительной чертой таких материалов является их многофункциональность. Доступность солевых форм для природных и синтетических полимеров, многие из которых являются полиэлектролитами, позволяет оказывать значительное влияние на ионный перенос в композиционной электродной массе, снижая поляризацию электродов и улучшая мощностные характеристики аккумуляторов. Способность образовывать «искусственный SEI» и/или формировать трёхмерную сетку с самовосстанавливающимися поперечными связями между макромолекулами делает возможным длительное безопасное циклирование, что особенно важно для активных материалов с очень большими изменениями объёма при интеркаляции/деинтеркаляции лития (например, кремния).
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