Фундаментальные проблемы преобразования энергии в литиевых электрохимических системах

Sodium trititanate, Na2Ti3O7, is considered to be a promising material for the negative electrode of reliable sodium-ion batteries. The advantages of Na2Ti3O7 include suitable electrode potential and cycling stability. However, this material is characterized by the limited specific capacity and low electronic conductivity. The current work is devoted to modification of Na2Ti3O7 by combining it with the high-capacity α-Fe2O3 phase.

The effect of the electrode sizes, the cell design and the compression force of the electrode modules on the impedance and discharge characteristics of lithium-sulfur cells was studied. It was shown that Swagelok and pouch cells with identical electrodes have different electrochemical characteristics – charge transfer resistance, discharge capacity and cycling duration. It was found that the discharge capacity at the first cycle of Swagelok and pouch cells differs by 20% approximately. The capacity of pouch cells decreases faster during cycling.

Germanium is an attractive element for the anodes in lithium-ion battery. The current article discusses the issue of the availability of raw material for the battery industry, particularly in relation to Russia.